Journal of Liaoning Petrochemical University
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Catalysts for Synthesis of Light Alkenes From Carbon Dioxide Through Hydrogenation With One-Step Method
TIAN Shi-chao, HAN Li-li,HOU Jun-qi,BIAN Wan-ying,TIAN Xiao-guang,LI Yong-chao,LIAN Pi-yong
Abstract672)      PDF (387KB)(449)      
 
CuO-ZnO/SAPO-34 composite catalyst was prepared by hydrothermal method, and applied in catalytic hydrogenation of carbon dioxide to light olefins in one-step process. CuO-ZnO was used to synthesis methanol from CO 2, while SAPO-34 molecular sieve take the catalytic role of methanol dehydration to light olefins. The properties and catalytic activity of composite catalyst were investigated by XRD, TEM, SEM, IR and fixed bed response evaluation. When the reaction condition is reaction temperature 270 ℃, the reaction pressure 3.5 MPa, molar ratio of hydrogen/carbon dioxide 4, volumetric space velocity 1 600 h -1, the catalyst shows good activity and selectivity. The conversion rate of CO 2 can reach 18.71%,and the yields of ethylene and propylene can reach 9.27% and 4.76%.
2011, 31 (3): 4-7. DOI: 10.3696/j.issn.1672-6952.2011.03.002
Continuously Selective Synthesis of Diethanolamine Catalyzed by B 2O 3/HZSM-5
ZHAO Xue-qin, ZHANG Zhao-fei, TONG Tian-yu, YIN Yan-chao,XIN Chun-ling,WANG Zhi-min, LIAN Pi-yong
Abstract512)      PDF (186KB)(257)      
 
B 2O 3/HZSM-5 catalyst was prepared by multiple impregnation, and used as a catalyst for synthesis of diethanolamine from anhydrous liquid ammonia and epoxyethane in a continuous fixed bed operation. Effect of boric acid amount on pore size and volume of the catalysts was studied and found that optimum B 2O 3 content is about 3%. Meanwhile, the reaction conditions are optimized and listed as follows: molar ratio of anhydrous liquid ammonia/epoxyethane 10∶3, reaction temperature 60 ℃, reaction pressure 1.0~3.0 MPa and volumetric space velocity 1.5 h -1. Under these conditions, the yield of diethanol amine could be reach 56%.
2011, 31 (2): 8-10. DOI: 10.3696/j.issn.1672-6952.2011.02.003